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Q.67 Chemistry ⭐ 360° Option Elimination Active
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NEET 2021 Chemistry Question 67 Solution

Topic: Solid State · Official NTA Booklet Code M1
NEET 2021 Chemistry Question 67: 14 Bravais Lattices: Count of Body-Centred Unit Cells

Question

The correct option for the number of body centred unit cells in all 14 types of Bravais lattice unit cells is:

✓
Verified Against NTA Final Answer Key
Option (4) : 3
📚 Solid State Easy
📋 Given Parameters & Problem Setup
Total Crystal Systems 7 crystal systems
Total Bravais Lattices 14 Bravais lattices
Target Unit Cell Type Body-centred unit cells (BCC)
⚡

The 30-Second Exam Hall Shortcut: ⚡ BCC Systems: Cubic, Tetragonal, Orthorhombic (Count = 3)

⏱️ Save ~20 seconds

Across all 7 crystal systems, body-centred lattices occur in exactly 3 systems: Cubic (11), Tetragonal (11), and Orthorhombic (11). No other system possesses a body-centred lattice! Total body-centred Bravais lattices =1+1+1=3= 1 + 1 + 1 = 3! Match Option (4)!

1 Total Bravais lattices = 14 across 7 crystal systems.
2 Recall distribution of Bravais types: - Primitive (P): in all 7 systems (7) - Body-centred (I): in Cubic, Tetragonal, Orthorhombic (3) - Face-centred (F): in Cubic, Orthorhombic (2) - End-centred (C): in Orthorhombic, Monoclinic (2) Total = 7 + 3 + 2 + 2 = 14.
3 Count of body-centred unit cells = 3.
4 Match Option (4).
🛡️
Why You Can 100% Trust This Shortcut: Canonical NCERT Solid State crystallography principle on 14 Bravais Lattices.
📐

Step-by-Step Rigorous Workflow & Mathematical Proof

Step 1

Reviewing the 14 Bravais Lattices across 7 Crystal Systems

Auguste Bravais demonstrated that only 14 space lattices are mathematically possible in three dimensions across the 7 crystal systems: 1. Cubic (3): Primitive, Body-centred, Face-centred 2. Tetragonal (2): Primitive, Body-centred 3. Orthorhombic (4): Primitive, Body-centred, Face-centred, End-centred 4. Hexagonal (1): Primitive 5. Rhombohedral / Trigonal (1): Primitive 6. Monoclinic (2): Primitive, End-centred 7. Triclinic (1): Primitive

Step 2

Enumerating Body-Centred Unit Cells

Summing the body-centred lattices: - Cubic body-centred: 1 - Tetragonal body-centred: 1 - Orthorhombic body-centred: 1 No other crystal system allows a body-centred Bravais lattice without reducing to a simpler existing lattice.

Total body-centred Bravais lattices=1+1+1=3\text{Total body-centred Bravais lattices} = 1 + 1 + 1 = 3
⭐

360° Option Elimination Engine Key Feature

Diagnose every choice: Know exactly why the right option works and why distractors fail.

4-Option Deep Scan
1 1
✗ Incorrect
Verdict & Scientific Reason:

7 is the number of PRIMITIVE unit cells (one in each crystal system), not body-centred.

⚠️
Student Fallacy (Why candidates pick this trap): Confusing primitive unit cell count with body-centred unit cell count.
2 2
✗ Incorrect
Verdict & Scientific Reason:

Arbitrary number.

⚠️
Student Fallacy (Why candidates pick this trap): Misremembering the Bravais lattice table.
3 3
✗ Incorrect
Verdict & Scientific Reason:

2 is the number of Face-centred (or End-centred) unit cells, not body-centred.

⚠️
Student Fallacy (Why candidates pick this trap): Confusing body-centred with face-centred Bravais lattices.
4 4
✓ 100% Correct
Verdict & Scientific Reason:

Exact count of body-centred unit cells: Cubic, Tetragonal, and Orthorhombic.

💡
Why this is airtight: None; precise Bravais lattice crystallography knowledge.
⚠️

NTA Trap Alert: Primitive vs. Body-Centred vs. Face-Centred Trap

The Bravais breakdown is: - Primitive = 7 - Body-centred = 3 - Face-centred = 2 - End-centred = 2 Total = 14. Students often confuse the counts of primitive (7) or face-centred (2) with body-centred (3).

🛡️ How to avoid the -1 mark: Mnemonic: "CTO has Body"   ⟹  \implies Cubic, Tetragonal, Orthorhombic = 3 systems.
📖

Core NEET Syllabus Standard

NCERT Chemistry · Solid State Standard Benchmark
Core Scientific Principle Tested:

"Only three crystal systems—cubic, tetragonal, and orthorhombic—possess body-centred Bravais lattices."

Syllabus Focus: Crystal Lattices and Unit Cells (14 Bravais Lattices)
✓ Core NEET UG Syllabus Anchor Syllabus & Academic Standards ↗

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⚖️ Legal & Fair Dealing Notice: Sourced from publicly released NEET 2021 question papers and NEET answer keys for private study, research, and non-commercial educational practice under Fair Dealing (Section 52(1)(a) of the Indian Copyright Act, 1957). Not affiliated with or endorsed by NTA or NMC.

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