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Q.66 Chemistry ⭐ 360° Option Elimination Active
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NEET 2021 Chemistry Question 66 Solution

Topic: Hydrogen · Official NTA Booklet Code M1
NEET 2021 Chemistry Question 66: Isotopes of Hydrogen: Radioactive Decay and Beta Emission of Tritium

Question

Tritium, a radioactive isotope of hydrogen, emits which of the following particles?

✓
Verified Against NTA Final Answer Key
Option (1) : Beta (β-)
📚 Hydrogen Easy
📋 Given Parameters & Problem Setup
Radioactive Isotope Tritium (3_1 H or T)
⚡

The 30-Second Exam Hall Shortcut: ⚡ NCERT Hydrogen Fact: Tritium Emits Low-Energy β⁻ Particles

⏱️ Save ~15 seconds

Verbatim NCERT Hydrogen: "Of these isotopes, only tritium is radioactive and emits low energy β−\beta^- particles (t1/2=12.33t_{1/2} = 12.33 years)." The nuclear transmutation is 13H→ 23He+β−+νˉe^3_1H \to\ ^3_2He + \beta^- + \bar{\nu}_e. Match Option (1)!

1 Recall hydrogen's three isotopes: Protium (11H^1_1H), Deuterium (12H^2_1H), and Tritium (13H^3_1H).
2 Only Tritium is radioactive, with high neutron-to-proton ratio (n/p=2/1=2n/p = 2/1 = 2).
3 To achieve nuclear stability, a neutron converts to a proton, emitting a negative beta particle (β−\beta^-) and an antineutrino.
4 Reaction: 13H⟶ 23He+ −10e^3_1H \longrightarrow\ ^3_2He +\ ^0_{-1}e (β−\beta^-).
5 Match Option (1).
🛡️
Why You Can 100% Trust This Shortcut: Canonical NCERT Hydrogen chapter section on Isotopes of Hydrogen.
📐

Step-by-Step Rigorous Workflow & Mathematical Proof

Step 1

Identifying the Isotopes of Hydrogen

Hydrogen has three naturally occurring isotopes: Protium (11H^1_1H), Deuterium (12H^2_1H or DD), and Tritium (13H^3_1H or TT). Protium and deuterium are non-radioactive stable isotopes, whereas tritium is unstable.

Step 2

Radioactivity and Mode of Decay of Tritium

Tritium contains 1 proton and 2 neutrons in its nucleus. The high neutron-to-proton ratio (n/p=2n/p = 2) places it above the nuclear stability belt. Stability is achieved by beta-minus (β−\beta^-) decay, in which a nuclear neutron transforms into a proton, an electron (beta particle), and an electron antineutrino:

13H⟶ 23He+ −10e  (β−)+νˉe^{3}_{1}\text{H} \longrightarrow\ ^{3}_{2}\text{He} +\ ^{0}_{-1}e\;(\beta^-) + \bar{\nu}_e
Step 3

Properties of Emitted Radiation

The emitted β−\beta^- particle has very low maximum kinetic energy (Emax≈18.6 keVE_{\text{max}} \approx 18.6\text{ keV}), and tritium has a half-life of t1/2=12.33 yearst_{1/2} = 12.33\text{ years}.

⭐

360° Option Elimination Engine Key Feature

Diagnose every choice: Know exactly why the right option works and why distractors fail.

4-Option Deep Scan
1 1
✓ 100% Correct
Verdict & Scientific Reason:

Verbatim NCERT fact: tritium decays via low-energy β−\beta^- emission.

💡
Why this is airtight: None; textbook nuclear chemistry recall.
2 2
✗ Incorrect
Verdict & Scientific Reason:

Alpha emission requires loss of a 24He^4_2He nucleus, impossible for a nucleus of mass 3.

⚠️
Student Fallacy (Why candidates pick this trap): Confusing heavy element decay (U, Ra) with light isotope decay.
3 3
✗ Incorrect
Verdict & Scientific Reason:

Tritium decay is a pure ground-state beta decay without accompanying gamma de-excitation.

⚠️
Student Fallacy (Why candidates pick this trap): Assuming all radioactive decays release gamma rays.
4 4
✗ Incorrect
Verdict & Scientific Reason:

Neutron emission does not occur spontaneously in tritium.

⚠️
Student Fallacy (Why candidates pick this trap): Assuming excess neutrons are expelled directly.
⚠️

NTA Trap Alert: Alpha vs. Beta Particle Trap

Students who associate radioactivity strictly with alpha particles often guess α\alpha (Option 2). A tritium nucleus has mass number 3, making it physically impossible to emit an alpha particle (mass 4).

🛡️ How to avoid the -1 mark: Tritium has A=3A=3. It emits a single β−\beta^- particle to convert into 3He^3He.
📖

Core NEET Syllabus Standard

NCERT Chemistry · Hydrogen Standard Benchmark
Core Scientific Principle Tested:

"Tritium is a radioactive isotope of hydrogen with a half-life of 12.33 years that decays by emitting low energy beta particles."

Syllabus Focus: Isotopes of Hydrogen
✓ Core NEET UG Syllabus Anchor Syllabus & Academic Standards ↗

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